The title compound, [Ti(C 4 H 9 N)Cl(C 5 H 5 N) 2 (C 7 H 11 N 2 )]ÁC 7 H 8 , has a mononuclear structure featuring a six-coordinate distorted octahedral titanium(IV) centre. The central Ti IV ion is coordinated by two N atoms from a dimethyl(1H-pyrrol-2-ylmethyl)amine molecule, two N atoms from two
Di-μ-chloro-bis[(N-tert-butylimido)chlorobis(pyridine-κN)titanium(IV)] perdeuterobenzene disolvate
✍ Scribed by Hazari, Nilay ;Cowley, Andrew R. ;Mountford, Philip
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 163 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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The dinuclear title compound, [Sn~2~(CH~3~)~2~(C~6~H~5~)~2~(C~7~H~3~NO~4~)~2~(H~2~O)~2~]·2CHCl~3~, crystallizes as a dichloroform solvate; the centrosymmetric compound has Sn in a seven-coordinate, __trans__-pentagonal–bipyramidal geometry. The dicarboxylate unit is tetradentate; it binds through th
Single-crystal X-ray study T = 100 K Mean (C-C) = 0.005 A Disorder in main residue R factor = 0.032 wR factor = 0.086 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.