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(N-tert-Butylimido)chlorido[dimethyl(1H-pyrrol-2-ylmethyl)amine-κ2N,N′]bis(pyridine-κN)titanium(IV) toluene solvate

✍ Scribed by Gong, Dao-Jun ;Wei, Hua ;Li, Ya-Hong

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
807 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Ti(C 4 H 9 N)Cl(C 5 H 5 N) 2 (C 7 H 11 N 2 )]ÁC 7 H 8 , has a mononuclear structure featuring a six-coordinate distorted octahedral titanium(IV) centre. The central Ti IV ion is coordinated by two N atoms from a dimethyl(1H-pyrrol-2-ylmethyl)amine molecule, two N atoms from two pyridine molecules, one N atom from a N-tert-butylimido ligand and one Cl atom.

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In the title compound, [Fe(C 12 H 12 N 4 )], the metal atom is fourcoordinated by four N atoms from the Schiff base ligand in an approximately square-planar configuration. The Fe-N distances are in the range 1.833 (3)-1.876 (3) A ˚. metal-organic papers Acta Cryst. (2006). E62, m2668-m2669 Ran et a

Dichlorido(N,N′-dibenzylideneethane-1,2-
Dichlorido(N,N′-dibenzylideneethane-1,2-diamine-κ2N,N′)[(2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanolato)-κ2O,O′]titanium(IV)
✍ Chen, Chien-An ;Chiang, Liang-Ying ;Gau, Han-Mou 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 450 KB

The title compound, [TiCl~2~(C~31~H~28~O~4~)(C~16~H~16~N~2~)], is a titanium(IV) complex of the bidentate 2,2-dimethyl-α,α,α′,α′-tetraphenyl-1,3-dioxolane-4,5-dimethanolate (TADDOLate) ligand containing also two chloride ions and a bidentate neutral __N__,__N__′-dibenzylideneethane-1,2-diamine ligan