The tetradentate Schiff base ligand derived from the condensation of pyrrole-2-carbaldehyde and cyclohexane-1,2-diamine forms a square-planar four-coordinate Ni complex, [Ni(C 16 H 18 N 4 )]. The compound crystallizes with two crystallographically independent molecules in the asymmetric unit.
[1,2-Bis(1H-pyrrol-2-ylmethyleneamino)ethane-κ4N]iron(II)
✍ Scribed by Ran, Jing-Wen ;Gong, Dao-Jun ;Li, Ya-Hong
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 92 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [Fe(C 12 H 12 N 4 )], the metal atom is fourcoordinated by four N atoms from the Schiff base ligand in an approximately square-planar configuration. The Fe-N distances are in the range 1.833 (3)-1.876 (3) A ˚.
metal-organic papers Acta Cryst. (2006). E62, m2668-m2669 Ran et al. [Fe(C 12 H 12 N 4 )] m2669
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 297 K Mean (C-C) = 0.005 A R factor = 0.050 wR factor = 0.131 Data-to-parameter ratio = 16.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
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