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catena-Poly[[bis[μ-1,4-bis(1,2,4-triazol-1-ylmethyl)benzene-κ2N4:N4′]copper(I)] perchlorate]

✍ Scribed by Lin, Jin ;Dong, Gui-Ying

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
1014 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The crystal structure of the title compound, {[Cu(C 12 H 12 N 6 )]-ClO 4 } n , consists of a one-dimensional cationic copper(I) chain and uncoordinated ClO 4 À anions. In the cationic chain, the Cu I center, which lies on a crystallographic twofold rotation axis, is coordinated by two N atoms from two 1,4-bis(1,2,4triazol-1-ylmethyl)benzene ligands, giving a linear coordination geometry, and the 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene ligand adopts a bis-monodentate bridging mode, linking Cu I atoms. The anion O atoms are disordered equally over two sites.

Related literature

The corresponding copper(II) coordination polymer has a double-stranded chain structure (Li et al., 2005).

📜 SIMILAR VOLUMES

catena-Poly­[[silver(I)-μ-4,4′-bi­pyridi
catena-Poly­[[silver(I)-μ-4,4′-bi­pyridine-κ2N:N′] perchlorate]
✍ Wang, Li-Shi ;Zhang, Jin-Feng ;Yang, Shi-Ping 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 140 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê Disorder in solvent or counterion R factor = 0.045 wR factor = 0.133 Data-to-parameter ratio = 20.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.