The crystal structure of the title compound, {[Cu(C 12 H 12 N 6 )]-ClO 4 } n , consists of a one-dimensional cationic copper(I) chain and uncoordinated ClO 4 À anions. In the cationic chain, the Cu I center, which lies on a crystallographic twofold rotation axis, is coordinated by two N atoms from t
catena-Poly[[copper(I)-μ-1,4-bis(imidazol-1-ylmethyl)benzene-κ2N:N′] perchlorate]
✍ Scribed by Li, Tao ;Du, Shao-Wu
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 277 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title complex, {[Ag(C~16~H~18~N~4~)]NO~3~}~__n__~, the cationic part forms infinite chains where the Ag^I^ ions are coordinated in a slightly bent fashion by two N-donor atoms of imidazole rings of two distinct ligand molecules. The nitrate anions interact weakly with the silver cations to fo
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê Disorder in solvent or counterion R factor = 0.045 wR factor = 0.133 Data-to-parameter ratio = 20.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.054 wR factor = 0.109 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.