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catena-Poly[[diiodo­cadmium(II)]-μ-1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene-κ2N4:N4′]

✍ Scribed by Niu, Yun-Yin ;Zhang, He-Li ;Hou, Hong-Wei ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
127 KB
Volume
61
Category
Article
ISSN
1600-5368

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catena-Poly[[bis[μ-1,4-bis(1,2,4-triazol
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The crystal structure of the title compound, {[Cu(C 12 H 12 N 6 )]-ClO 4 } n , consists of a one-dimensional cationic copper(I) chain and uncoordinated ClO 4 À anions. In the cationic chain, the Cu I center, which lies on a crystallographic twofold rotation axis, is coordinated by two N atoms from t

Poly[[cyanato­cobalt(II)]bis­[μ-1,4-bis­
Poly[[cyanato­cobalt(II)]bis­[μ-1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene]]
✍ Shen, Xiao-Ping ;Zhou, Hu 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 256 KB

The coordination geometry of the Co II atom in the title complex, [Co(NCO) 2 (C 12 H 12 N 6 ) 2 ] n or [Co(NCO) 2 (bbtz) 2 ] n , where bbtz is 1,4-bis(1,2,4-triazol-1-methyl)benzene, is distorted octahedral, in which the Co II atom lies on an inversion centre and is coordinated by four N atoms from