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Poly[[cyanatocobalt(II)]bis[μ-1,4-bis(1,2,4-triazol-1-ylmethyl)benzene]]

✍ Scribed by Shen, Xiao-Ping ;Zhou, Hu

Publisher: International Union of Crystallography
Year: 2006
Tongue: English
Weight: 256 KB
Volume: 62
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536806050148

No coin nor oath required. For personal study only.

✦ Synopsis

The coordination geometry of the Co II atom in the title complex, [Co(NCO) 2 (C 12 H 12 N 6 ) 2 ] n or [Co(NCO) 2 (bbtz) 2 ] n , where bbtz is 1,4-bis(1,2,4-triazol-1-methyl)benzene, is distorted octahedral, in which the Co II atom lies on an inversion centre and is coordinated by four N atoms from the triazole rings of four symmetry-related bbtz ligands and two N atoms from two symmetry-related monodentate NCO À ligands. The Co II atoms are bridged by four bbtz ligands to form a twodimensional (4,4)-network.

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✦ Synopsis

Poly[[cyanatocobalt(II)]bis[μ-1,4-bis(1,2,4-triazol-1-ylmethyl)benzene]]