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Poly[bis­[μ-1,4-bis­(imidazol-1-yl)butane]dicyanato­nickel(II)]

✍ Scribed by Zhu, Xia ;Zhang, Yu-Mei ;Li, Bao-Long ;Zhang, Yong

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
153 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The coordination geometry of the Ni^II^ atom in the title complex, [Ni(NCO)~2~(C~10~H~14~N~4~)~2~]~n~ or [Ni(NCO)~2~(bimb)~2~]~n~, where bimb is 1,4-bis(imidazol-1-yl)butane, is distorted octahedral, in which the Ni^II^ atom lies on an inversion centre, coordinated by four N atoms from the imidazole rings of four symmetry-related bimb ligands in the equatorial positions and two N atoms of two symmetry-related NCO^−^ ligands in the axial positions. The Ni^II^ atoms are bridged by four bimb ligands to form a two-dimensional (4,4)-network.

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