𝔖 Bobbio Scriptorium
✦   LIBER   ✦

catena-Poly[[[aquazinc(II)]-bis[μ-(p-phenylenedioxy)diacetato]-zinc(II)-μ-1,4-bis(1H-imidazol-l-yl)butane] dihydrate]

✍ Scribed by Lv, Ming

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
482 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the title compound, {[Zn~2~(C~10~H~8~O~6~)~2~(C~10~H~14~N~4~)(H~2~O)~2~]·2H~2~O}~n~, the Zn^II^ atom is six-coordinated by one N atom from one 1,4-bis(1__H__-imidazol-l-yl)butane ligand and five O atoms from two different (p-phenylenedioxy)diacetate ligands and one water molecule in a very distorted ZnNO~5~ octahedral environment. Two (p-phenylenedioxy)diacetate ligands bridge two Zn^II^ atoms to form a dimer. The dimers are further linked by the centrosymmetric 1,4-bis(1__H__-imidazol-l-yl)butane ligands, thus forming a chain structure. O—H...O hydrogen bonds link the chains, forming a three-dimensional supramolecular network.

📜 SIMILAR VOLUMES

Poly[bis­[μ-1,4-bis­(imidazol-1-yl)butan
Poly[bis­[μ-1,4-bis­(imidazol-1-yl)butane]dicyanato­nickel(II)]
✍ Zhu, Xia ;Zhang, Yu-Mei ;Li, Bao-Long ;Zhang, Yong 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 153 KB

The coordination geometry of the Ni^II^ atom in the title complex, [Ni(NCO)~2~(C~10~H~14~N~4~)~2~]~__n__~ or [Ni(NCO)~2~(bimb)~2~]~__n__~, where bimb is 1,4-bis(imidazol-1-yl)butane, is distorted octahedral, in which the Ni^II^ atom lies on an inversion centre, coordinated by four N atoms from the i

catena-Poly[[[bis(2-methyl-1H-imidazole-
catena-Poly[[[bis(2-methyl-1H-imidazole-κN3)cadmium(II)]-μ-cyclohexane-1,4-dicarboxylato] dihydrate]
✍ Li, Yuan-Jing 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 871 KB

In the title compound, {[Cd(C 8 H 10 O 2 )(C 4 H 6 N 2 ) 2 ]Á2H 2 O} n , each Cd II atom is six-coordinated by two N atoms from two 2-methyl-1H-imidazole (mi) molecules and four O atoms from two cyclohexane-1,4-dicarboxylate (1,4-chdc) ligands in a distorted octahedral environment. The asymmetric un