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{μ-1,4-Bis[2-(2-pyrid­yl)imidazol-1-yl]butane}bis­[dichloro­copper(II)]

✍ Scribed by Lan, Ya-Qian ;Fu, Yao-Mei ;Shao, Kui-Zhan ;Su, Zhong-Min


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
80 KB
Volume
62
Category
Article
ISSN
1600-5368

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The coordination geometry of the Ni^II^ atom in the title complex, [Ni(NCO)~2~(C~10~H~14~N~4~)~2~]~__n__~ or [Ni(NCO)~2~(bimb)~2~]~__n__~, where bimb is 1,4-bis(imidazol-1-yl)butane, is distorted octahedral, in which the Ni^II^ atom lies on an inversion centre, coordinated by four N atoms from the i

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The title compound, C 18 H 18 N 4 , lies on an inversion center. The benzimidazolyl moiety is essentially planar. Intermolecular NÐHÁ Á ÁN hydrogen bonds give rise to an in®nite helical chain structure, with the chains stacked by CÐHÁ Á Á% and %Á Á Á% interactions.