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Bis[μ-2-(1H-imidazol-2-yl)phenolato]bis­[chloro­methano­lcopper(II)]

✍ Scribed by He, Hong-Shan

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
153 KB
Volume
62
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES

Bis[2-(1H-imidazol-2-yl)phenolato-κ2N,O]
Bis[2-(1H-imidazol-2-yl)phenolato-κ2N,O]zinc(II) methanol solvate
✍ He, Hong-Shan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 184 KB

In the title complex, [Zn(C 18 H 14 N 4 O 2 )]ÁCH 3 OH, two anionic 2-(1H-imidazol-2-yl)phenolate bidentate ligands coordinate through the phenolate O and imidazolyl N atoms to the central Zn II atom to give a four-coordinate tetrahedral geometry.

Bis[2-(4,5-dihydro-1H-imidazol-2-yl)phen
Bis[2-(4,5-dihydro-1H-imidazol-2-yl)phenolato-κ2N,O]nickel(II)
✍ He, Hong-Shan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 125 KB

In the title complex, [Ni(C 9 H 9 N 2 O) 2 ], the Ni 2+ ion is coordinated by two 2-(4,5-dihydro-1H-imidazol-2-yl)phenolate ligands. Each ligand provides one O atom and one N atom to the Ni coordination, giving a total coordination number of 4. The centrosymmetric complex adopts a square-planar geom

Bis{μ2-2-[2-(dimethyl­amino)ethyl­imino­
Bis{μ2-2-[2-(dimethyl­amino)ethyl­imino­methyl]phenolato}bis­[chloro­zinc(II)]
✍ Chen, Hsuan-Ying ;Lin, Chu-Chieh 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 131 KB

The title complex, [Zn~2~(C~11~H~15~N~2~O)~2~Cl~2~] or [__L__ZnCl]~2~, where __L__ is the 2-[2-(dimethylamino)ethyliminomethyl]phenolate anion, is obtained by the reaction of __L__ZnEt with CDCl~3~ or by the reaction of __L__H with ZnCl~2~ in refluxing tetrahydrofuran. The Zn atoms in the dimeric co