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Bis{μ-N-[(1-methyl­imidazol-2-yl)­methyl]-β-alanine}bis­[di­chloro­zinc(II)] dihydrate

✍ Scribed by Yang, Shi-Ping ;Chen, Hong-Mei ;Zhang, Fan ;Chen, Qiong Qiong ;Yu, Xi-Bin

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
161 KB
Volume
60
Category
Article
ISSN
1600-5368

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In the title compound, (C 5 H 14 N 2 ) 2 [Bi 2 Cl 10 ]Á2H 2 O, each Bi III atom of the centrosymmetric anion is six-coordinate in a distorted octahedral geometry. The salt adopts a threedimensional network arising from the hydrogen bonds between the cations, anions and water molecules.

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The title compound, [ZnCl 2 (C 16 H 20 N 4 )] n , was prepared from the reaction of N,N H -bis(4-pyridylmethyl)piperazine (bpmp) and ZnCl 2 . The asymmetric unit contains one Cl atom, half a Zn II ion and half a bmpb moiety. The Zn II ion, which lies on a twofold axis, has a distorted tetrahedral co