The title salt, (C 4 H 12 N 2 ) 2 [Bi 2 Cl 10 ]Á3H 2 O, was prepared by reaction of bismuth trichloride and piperazine in a hydrochloric acid medium. It consists of piperazinium dications and dimeric [Bi 2 Cl 10 ] 4À tetraanions, the latter with twofold rotation symmetry, together with water of crys
✦ LIBER ✦
Bis[N-methylpiperidinium(2+)] di-μ-chloro-bis[tetrachlorobismuthate(III)] dihydrate
✍ Scribed by Fu, Yun-Long ;Xu, Zhi-Wei ;Ren, Jia-Lin ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 145 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title compound, (C 5 H 14 N 2 ) 2 [Bi 2 Cl 10 ]Á2H 2 O, each Bi III atom of the centrosymmetric anion is six-coordinate in a distorted octahedral geometry. The salt adopts a threedimensional network arising from the hydrogen bonds between the cations, anions and water molecules.
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