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Bis[N-methyl­piperidinium(2+)] di-μ-chloro-bis­[tetra­chloro­bismuthate(III)] dihydrate

✍ Scribed by Fu, Yun-Long ;Xu, Zhi-Wei ;Ren, Jia-Lin ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
145 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, (C 5 H 14 N 2 ) 2 [Bi 2 Cl 10 ]Á2H 2 O, each Bi III atom of the centrosymmetric anion is six-coordinate in a distorted octahedral geometry. The salt adopts a threedimensional network arising from the hydrogen bonds between the cations, anions and water molecules.


📜 SIMILAR VOLUMES


Bis(piperazinium) di-μ-chloro-bis­[tetra
✍ Wu, Ping-Fan ;Tan, Xiao-Feng ;Meng, Xiang-Gao ;Li, Dong-Sheng ;Zhu, Yu-Lin ;Wei, 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 188 KB

The title salt, (C 4 H 12 N 2 ) 2 [Bi 2 Cl 10 ]Á3H 2 O, was prepared by reaction of bismuth trichloride and piperazine in a hydrochloric acid medium. It consists of piperazinium dications and dimeric [Bi 2 Cl 10 ] 4À tetraanions, the latter with twofold rotation symmetry, together with water of crys