The title salt, (C 4 H 12 N 2 ) 2 [Bi 2 Cl 10 ]Á3H 2 O, was prepared by reaction of bismuth trichloride and piperazine in a hydrochloric acid medium. It consists of piperazinium dications and dimeric [Bi 2 Cl 10 ] 4À tetraanions, the latter with twofold rotation symmetry, together with water of crys
Bis(piperazinium) di-μ-chloro-pentachlorotriiododibismuthate(III) tetrahydrate
✍ Scribed by Wu, Ping-Fan ;Meng, Xiang-Gao ;Chen, Wen-Jia ;Li, Dong-Sheng ;Wei, Yong-Ge
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 252 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, (C 5 H 14 N 2 ) 2 [Bi 2 Cl 10 ]Á2H 2 O, each Bi III atom of the centrosymmetric anion is six-coordinate in a distorted octahedral geometry. The salt adopts a threedimensional network arising from the hydrogen bonds between the cations, anions and water molecules.
In the cation of the title compound, [Rh 2 Cl 3 (C 10 H 15 ) 2 ]BF 4 , two Rh( 5 -C 5 Me 5 ) fragments are linked by three bridging Cl atoms. Each rhodium center has a pseudo-octahedral coordination geometry, with a C 5 Me 5 group occupying three positions and three Cl atoms completing the coordinat