In the title compound, (C 9 H 8 N) [FeCl 4 ], the tetrachloroferrate(III) anion lies on a mirror plane, whereas the quinolinium cation has inversion symmetry as the result of orientational disorder. In the crystal structure, C-HÁ Á ÁCl interactions between the ions form zigzag ribbons along the b ax
Bis(2-methylquinolinium) tetrachloroferrate(III) chloride
✍ Scribed by Wyrzykowski, Dariusz ;Sikorski, Artur ;Lis, Tadeusz ;Konitz, Antoni ;Warnke, Zygmunt
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 313 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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The title compound, [Fe(C 10 H 8 N 2 ) 3 ][FeCl 4 ] 2 , consists of a pseudo-octahedral tris(2,2 H -bipyridyl)iron(II) cation and two pseudo-tetrahedral tetrachloroferrate(III) anions.
In the title compound, (C 5 H 14 N 2 ) 2 [Bi 2 Cl 10 ]Á2H 2 O, each Bi III atom of the centrosymmetric anion is six-coordinate in a distorted octahedral geometry. The salt adopts a threedimensional network arising from the hydrogen bonds between the cations, anions and water molecules.
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.004 A Ê R factor = 0.040 wR factor = 0.120 Data-to-parameter ratio = 16.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.