Bis[2-(1-methyl-1H-imidazol-2-yl-3-iosulfanyl)-6-(1-methyl-1H-imidazol-2-ylsulfanyl)pyridine] tetrachloroferrate tetrafluoroborate
✍ Scribed by Lewis, Gareth R. ;Hubberstey, Peter ;Sampson, Claire L.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 600 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, C 13 H 13 N 5 Á1.5H 2 O, was synthesized by the reaction of 2,6-bis(bromomethyl)pyridine with imidazole. The asymmetric unit contains two crystallographically independent 2,6-bis(1H-imidazol-1-ylmethyl)pyridine molecules and three water molecules. The crystal packing is stabilize
ÁBr À ÁH 2 O, was determined at 150 K. It is a supramolecular adduct of imidazolium bromide and water molecules. Helical chains of (H 2 OÁBr À ) exist in the structure along the [001] direction. Each chain forms extensive hydrogen bonds with the imidazolium cations.