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Bis­[2-(1-methyl-1H-imidazol-2-yl-3-iosulfanyl)-6-(1-methyl-1H-imidazol-2-yl­sulfanyl)­pyridine] tetra­chloro­ferrate tetra­fluoro­borate

✍ Scribed by Lewis, Gareth R. ;Hubberstey, Peter ;Sampson, Claire L.


Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
600 KB
Volume
58
Category
Article
ISSN
1600-5368

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2,6-Bis(1H-imidazol-1-ylmeth­yl)pyridine
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The title compound, C 13 H 13 N 5 Á1.5H 2 O, was synthesized by the reaction of 2,6-bis(bromomethyl)pyridine with imidazole. The asymmetric unit contains two crystallographically independent 2,6-bis(1H-imidazol-1-ylmethyl)pyridine molecules and three water molecules. The crystal packing is stabilize

1-(6-Bromo­pyridin-2-yl)-3-methyl-3H-imi
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ÁBr À ÁH 2 O, was determined at 150 K. It is a supramolecular adduct of imidazolium bromide and water molecules. Helical chains of (H 2 OÁBr À ) exist in the structure along the [001] direction. Each chain forms extensive hydrogen bonds with the imidazolium cations.