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Tris(2,2′-bipyridyl-N,N′)­iron(II) bis[tetra­chloro­ferrate(III)]

✍ Scribed by Ariyananda, L. Mihiri D. ;Norman, Richard E.


Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
232 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, [Fe(C 10 H 8 N 2 ) 3 ][FeCl 4 ] 2 , consists of a pseudo-octahedral tris(2,2 H -bipyridyl)iron(II) cation and two pseudo-tetrahedral tetrachloroferrate(III) anions.


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Tris(2,2′-bipyridyl-κ2N,N′)copper(II) he
✍ Wang, Li ;Yang, Xue-Yun ;Huang, Wei 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 311 KB

The title compound, [Cu(C~10~H~8~N~2~)~3~](PF~6~)~2~, is a six-coordinate copper(II) complex with a slightly tetragonally elongated octahedral coordination geometry. There are weak C—H...F, C—H...N and π–π stacking interactions in the structure.