Quinolinium tetrachloroferrate(III)
✍ Scribed by Wyrzykowski, Dariusz ;Sikorski, Artur ;Konitz, Antoni ;Warnke, Zygmunt
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 284 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, (C 9 H 8 N) [FeCl 4 ], the tetrachloroferrate(III) anion lies on a mirror plane, whereas the quinolinium cation has inversion symmetry as the result of orientational disorder. In the crystal structure, C-HÁ Á ÁCl interactions between the ions form zigzag ribbons along the b axis. These ribbons are linked via Fe-ClÁ Á Á interactions, forming a three-dimensional network.
📜 SIMILAR VOLUMES
The title compound, [Fe(C 10 H 8 N 2 ) 3 ][FeCl 4 ] 2 , consists of a pseudo-octahedral tris(2,2 H -bipyridyl)iron(II) cation and two pseudo-tetrahedral tetrachloroferrate(III) anions.