In the title compound, (C 9 H 8 N) [FeCl 4 ], the tetrachloroferrate(III) anion lies on a mirror plane, whereas the quinolinium cation has inversion symmetry as the result of orientational disorder. In the crystal structure, C-HÁ Á ÁCl interactions between the ions form zigzag ribbons along the b ax
✦ LIBER ✦
Matrinium tetrachloroferrate(III)
✍ Scribed by Jin, Zhi-Min ;Li, Zu-Guang ;Li, Li ;Li, Mei-Chao ;Hu, Mao-Lin
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 224 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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The synthesis of the title compound, (C 7 H 9 N 2 )[GaCl 4 ], is described. The N-C-N fragment involves delocalized bonding, which does not extend to the adjacent C-C bond. The N-C-N plane is aligned at 39.6 (2) to the mean plane through the phenyl group. The GaCl 4 À anion is tetrahedral, with Ga-