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Benzamidinium tetra­chloro­gallate(III)

✍ Scribed by Barker, James ;Errington, William ;Wallbridge, Malcolm G. H.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
105 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The synthesis of the title compound, (C 7 H 9 N 2 )[GaCl 4 ], is described. The N-C-N fragment involves delocalized bonding, which does not extend to the adjacent C-C bond. The N-C-N plane is aligned at 39.6 (2) to the mean plane through the phenyl group. The GaCl 4

À anion is tetrahedral, with Ga-Cl bonds in the range 2.165 (1)-2.180 (1) A ˚. Intermolecular hydrogen bonding is postulated between the N and Cl atoms.

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