Tetramethylammonium tetraaquadichlorochromium(III) trichloride dihydrate
✍ Scribed by Eriksson, Annika K. ;Casari, Barbara M. ;Langer, Vratislav
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 432 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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Acta Cryst. (2005). E61, m2733-m2735 Artali et al. (C 4 H 12 N)[Sb(C 6 H 5 ) 2 Cl(NCS)] m2735
In the title compound, (C 5 H 14 N 2 ) 2 [Bi 2 Cl 10 ]Á2H 2 O, each Bi III atom of the centrosymmetric anion is six-coordinate in a distorted octahedral geometry. The salt adopts a threedimensional network arising from the hydrogen bonds between the cations, anions and water molecules.
The Hf IV atoms in the centrosymmetric title compound, (C 4 H 12 N) 2 ][Hf 2 F 10 (H 2 O) 2 ], are bridged by two F atoms. The Hf IV atoms show pentagonal-bipyramidal coordination. The dianions are linked by water-fluorine hydrogen bonds into layers.
In the crystal structure of the title compound, [Co(NO 2 )-(C 44 H 28 N 4 )(H 2 O)]ÁCH 2 Cl 2 , the Co III atom has a distorted octahedral coordination, with the water molecule trans to the nitro ligand. The CoÐN(nitro) and CoÐO(aqua) bond distances are 1.863 (8) and 2.114 (8) A Ê , respectively. Th