Tetramethylammonium dichlorodiphenylbismuthate(III)
✍ Scribed by Charmant, Jonathan P. H. ;Orpen, A. Guy ;James, Sian C. ;Norman, Nicholas C. ;Starbuck, Jonathan
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 179 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, (C 5 H 14 N 2 ) 2 [Bi 2 Cl 10 ]Á2H 2 O, each Bi III atom of the centrosymmetric anion is six-coordinate in a distorted octahedral geometry. The salt adopts a threedimensional network arising from the hydrogen bonds between the cations, anions and water molecules.
The title salt, (C 4 H 12 N 2 ) 2 [Bi 2 Cl 10 ]Á3H 2 O, was prepared by reaction of bismuth trichloride and piperazine in a hydrochloric acid medium. It consists of piperazinium dications and dimeric [Bi 2 Cl 10 ] 4À tetraanions, the latter with twofold rotation symmetry, together with water of crys
Single-crystal X-ray study T = 160 K Mean '(C±C) = 0.006 A Ê R factor = 0.044 wR factor = 0.118 Data-to-parameter ratio = 21.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Acta Cryst. (2005). E61, m2733-m2735 Artali et al. (C 4 H 12 N)[Sb(C 6 H 5 ) 2 Cl(NCS)] m2735