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Aqua­nitro(α,β,γ,δ-tetra­phenyl­porphyrinato)­cobalt(III) di­chloro­methane solvate

✍ Scribed by Ohba, Shigeru ;Seki, Hiroshi

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
311 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the crystal structure of the title compound, [Co(NO 2 )-(C 44 H 28 N 4 )(H 2 O)]ÁCH 2 Cl 2 , the Co III atom has a distorted octahedral coordination, with the water molecule trans to the nitro ligand. The CoÐN(nitro) and CoÐO(aqua) bond distances are 1.863 (8) and 2.114 (8) A Ê , respectively. There is no intermolecular hydrogen bond involving the aqua ligand.

📜 SIMILAR VOLUMES

Nitro(α,β,γ,δ-tetra­phenyl­porphyrinato)
Nitro(α,β,γ,δ-tetra­phenyl­porphyrinato)­cobalt(III) benzene solvate
✍ Ohba, Shigeru ;Seki, Hiroshi 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 388 KB

In the crystal structure of the title compound, [Co(C 44 H 28 N 4 )-(NO 2 )]ÁC 6 H 6 , the Co III atom has a distorted square±pyramidal coordination, with the nitro ligand at the apical position. The CoÐN(nitro) bond distance is 1.880 (3) A Ê .

(Ethanol-O)­nitro(α,β,γ,δ-tetra­phenyl­p
(Ethanol-O)­nitro(α,β,γ,δ-tetra­phenyl­porphyrinato)­cobalt(III)
✍ Ohba, Shigeru ;Seki, Hiroshi 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 323 KB

Single-crystal X-ray study T = 297 K Mean '(C±C) = 0.004 A Ê H-atom completeness 83% Disorder in main residue R factor = 0.039 wR factor = 0.112 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.