𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Potassium tetra­chloro­gallate

✍ Scribed by Gorlov, Mikhail ;Fischer, Andreas ;Kloo, Lars


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
198 KB
Volume
59
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis


From a solution of potassium tetrachloroplatinate and gallium trichloride in benzene, potassium tetrachlorogallate, K[GaCl 4 ], could be crystallized and its structure determined. The crystal structure is isotypic with Ga[AlCl 4 ]. It consists of tetrahedral anions GaCl 4 À and potassium cations which are coordinated by Cl À in a tricapped trigonal prismatic geometry.


📜 SIMILAR VOLUMES


Benzamidinium tetra­chloro­gallate(III)
✍ Barker, James ;Errington, William ;Wallbridge, Malcolm G. H. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 105 KB

The synthesis of the title compound, (C 7 H 9 N 2 )[GaCl 4 ], is described. The N-C-N fragment involves delocalized bonding, which does not extend to the adjacent C-C bond. The N-C-N plane is aligned at 39.6 (2) to the mean plane through the phenyl group. The GaCl 4 À anion is tetrahedral, with Ga-

n-Propyl gallate–chloro­form (3/0.5)
✍ Iwata, Shohei ;Hitachi, Akio ;Makino, Takashi ;Mizuguchi, Jin 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 198 KB
Tetra­butyl­ammonium aqua­tetra­chloro­o
✍ Wu, Chuan-De ;Zhang, Quan-Zheng ;Lu, Can-Zhong ;Zhuang, Hong-Hui ;Huang, Jin-Shu 📂 Article 📅 2001 🏛 International Union of Crystallography 🌐 English ⚖ 346 KB

packing of the cations and anions in the crystal structure, there are no other signi®cant interactions (Fig. 2).

Bis­(tetra­methyl­ammonium) tetra­chloro
✍ Fábry, Jan ;Krupková, Radmila ;Vaněk, Přemysl ;Dušek, Michal ;Němec, Ivan 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 217 KB

The structure of a room-temperature phase of bis(tetramethylammonium) tetrachloropalladate(II), (C 4 H 12 N) 2 -[PdCl 4 ], is reported. All the H atoms were observed in a Fourier map. The presence of CÐHÁ Á ÁCl hydrogen bonds, with HÁ Á ÁCl distances as short as 2.92 A Ê , was con®rmed by vibrationa