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Di-μ-chloro-bis­[chloro­(dipyridophenazine-κ2N,N′)copper(II)]

✍ Scribed by Han, Zheng-Bo

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
136 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

Di-l-chloro-bis[chloro(dipyridophenazinej 2 N,N 0 0 0 )copper(II)]

📜 SIMILAR VOLUMES

(2,2′-Bi­pyridine-κ2N,N′)­di­chloro­copp
(2,2′-Bi­pyridine-κ2N,N′)­di­chloro­copper(II)
✍ Wang, Yan-Qin ;Bi, Wen-Hua ;Li, Xing ;Cao, Rong 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 357 KB

The title compound, [CuCl 2 (C 10 H 8 N 2 )], has twofold symmetry and the coordination geometry around the Cu II atom is distorted square-planar. There are weak intermolecular CuÁ Á ÁCl interactions, forming a chain structure in the crystal.

Di-μ-chloro-bis­[(2,2-bipyridine)chloro­
Di-μ-chloro-bis­[(2,2-bipyridine)chloro­copper(II)]
✍ Kostakis, George E. ;Nordlander, Ebbe ;Haukka, Matti ;Plakatouras, John C. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 230 KB

The title compound, [Cu 2 Cl 4 (C 10 H 8 N 2 ) 2 ], represents the first example of a simple dimeric coordination complex of Cu II and 2,2 0 -bipyridine (bpy). The metal is in a five-coordinate distorted square-pyramidal environment, bonded to a 2,2 0bipyridine molecule, two bridging chlorides and o