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Di-μ-chloro-bis­[(2,2-bipyridine)chloro­copper(II)]

✍ Scribed by Kostakis, George E. ;Nordlander, Ebbe ;Haukka, Matti ;Plakatouras, John C.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
230 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Cu 2 Cl 4 (C 10 H 8 N 2 ) 2 ], represents the first example of a simple dimeric coordination complex of Cu II and 2,2 0 -bipyridine (bpy). The metal is in a five-coordinate distorted square-pyramidal environment, bonded to a 2,2 0bipyridine molecule, two bridging chlorides and one terminal chloride. There is a centre of symmetry at the mid-point of the CuÁ Á ÁCu vector.

📜 SIMILAR VOLUMES

Di-μ-chloro-bis{chloro­[1,2-di­phenyl-2-
Di-μ-chloro-bis{chloro­[1,2-di­phenyl-2-(phenyl­amino)­ethano­ximato]copper(II)}
✍ Puschmann, Horst ;Batsanov, Andrei S. ;Howard, Judith A. K. ;Soto, Bernardino ;B 📂 Article 📅 2001 🏛 International Union of Crystallography 🌐 English ⚖ 203 KB

The title compound, [Cu 2 Cl 4 (C 20 H 18 N 2 O) 2 ], is a centrosymmetric dimer bridged through the Cl atoms. The bridging Cu 2 Cl 2 unit is planar and each Cu II ion has two different distances to the bridging Cl atom. The Cu II ions are coordinated to three Cl and two N atoms in a squarepyramidal