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Di-μ-chloro-bis{chloro­[1,2-di­phenyl-2-(phenyl­amino)­ethano­ximato]copper(II)}

✍ Scribed by Puschmann, Horst ;Batsanov, Andrei S. ;Howard, Judith A. K. ;Soto, Bernardino ;Bonne, Raul ;Au-Alvarez, Oscar


Publisher
International Union of Crystallography
Year
2001
Tongue
English
Weight
203 KB
Volume
57
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, [Cu 2 Cl 4 (C 20 H 18 N 2 O) 2 ], is a centrosymmetric dimer bridged through the Cl atoms. The bridging Cu 2 Cl 2 unit is planar and each Cu II ion has two different distances to the bridging Cl atom. The Cu II ions are coordinated to three Cl and two N atoms in a squarepyramidal disposition. Hydrogen bonds are formed by ±OH and ±NH with the Cl atoms.


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