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Di-μ-chloro-bis{chloro­[1,2-di­phenyl-2-(4-chloro­phenyl­amino)­ethano­ximato]copper(II)}

✍ Scribed by Puschmann, Horst ;Howard, Judith A. K. ;Soto, Bernardino ;Bonne, Raul ;Au-Alvarez, Oscar

Publisher
International Union of Crystallography
Year
2001
Tongue
English
Weight
198 KB
Volume
57
Category
Article
ISSN
1600-5368

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The title compound, [Cu 2 Cl 4 (C 10 H 8 N 2 ) 2 ], represents the first example of a simple dimeric coordination complex of Cu II and 2,2 0 -bipyridine (bpy). The metal is in a five-coordinate distorted square-pyramidal environment, bonded to a 2,2 0bipyridine molecule, two bridging chlorides and o

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The title compound, C 32 H 23 Cl 2 N, was synthesized via the Ullmann reaction. The orientations of the three aromatic rings attached to the vinyl group are determined by the sp 2 state of the vinyl C atoms. The crystal packing is stabilized by weak CÐHÁ Á Á% interactions.