Bis(4-chlorophenyl)[4-(2,2-diphenylvinyl)phenyl]amine
✍ Scribed by Cao, Xiao-Dan ;Liu, Dong-Zhi ;Zhou, Xue-Qin
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 159 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 32 H 23 Cl 2 N, was synthesized via the Ullmann reaction. The orientations of the three aromatic rings attached to the vinyl group are determined by the sp 2 state of the vinyl C atoms. The crystal packing is stabilized by weak CÐHÁ Á Á% interactions.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.002 A Ê R factor = 0.038 wR factor = 0.102 Data-to-parameter ratio = 10.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The asymmetric biphenyl title compound, C 14 H 13 ClO 2 , exhibits a significant twist of ca 30 about the central C-C bond.
The dihedral angle between the benzene rings in the title compound, C 12 H 7 Cl 3 , is 47.25 (4) .