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An asymmetric bi­phenyl compound: 3-chloro-4,4′-di­methoxy­bi­phenyl

✍ Scribed by Tan, Ting-Feng ;Zhang, Jian-Xin ;Meng, Ji-Ben


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
123 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


The asymmetric biphenyl title compound, C 14 H 13 ClO 2 , exhibits a significant twist of ca 30 about the central C-C bond.


📜 SIMILAR VOLUMES


4,4′-Bis­[2,2-bis(4-methoxy­phenyl)­ethe
✍ Vande Velde, Christophe M. L. ;Hoefnagels, Roel ;Geise, Herman J. 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 239 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.002 A Ê R factor = 0.038 wR factor = 0.102 Data-to-parameter ratio = 10.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The title compound, C 32 H 23 Cl 2 N, was synthesized via the Ullmann reaction. The orientations of the three aromatic rings attached to the vinyl group are determined by the sp 2 state of the vinyl C atoms. The crystal packing is stabilized by weak CÐHÁ Á Á% interactions.

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H -Dicyanobiphenyl, C 14 H 8 N 2 , has a normal structure with a twist angle of 31.8 (2) . The molecules stack with overlapping % systems and form chains held together by antiparallel CÐ NÁ Á ÁCÐN interactions. In addition, there are a number of CÐ HÁ Á ÁN interactions.

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The dihedral angle between the benzene rings in the title compound, C 12 H 7 Cl 3 , is 47.25 (4) .