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catena-Poly­[[di­chloro­zinc(II)]-μ-N,N′-bis(4-pyridyl­methyl)­piperazine]

✍ Scribed by Li, Xiao-Ju ;Cao, Rong ;Li, Xing ;Bi, Wen-Hua ;Wang, Yan-Qin

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
302 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [ZnCl 2 (C 16 H 20 N 4 )] n , was prepared from the reaction of N,N H -bis(4-pyridylmethyl)piperazine (bpmp) and ZnCl 2 . The asymmetric unit contains one Cl atom, half a Zn II ion and half a bmpb moiety. The Zn II ion, which lies on a twofold axis, has a distorted tetrahedral coordination geometry, with the central piperazine group in bpmp bridging ZnCl 2 units to form a one-dimensional polymeric chain. The piperazine connector in bpmp adopts a stable chair conformation.

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