𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bis{μ2-2-[2-(dimethyl­amino)ethyl­imino­methyl]phenolato}bis­[chloro­zinc(II)]

✍ Scribed by Chen, Hsuan-Ying ;Lin, Chu-Chieh

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
131 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title complex, [Zn~2~(C~11~H~15~N~2~O)~2~Cl~2~] or [__L__ZnCl]~2~, where L is the 2-[2-(dimethylamino)ethyliminomethyl]phenolate anion, is obtained by the reaction of __L__ZnEt with CDCl~3~ or by the reaction of __L__H with ZnCl~2~ in refluxing tetrahydrofuran. The Zn atoms in the dimeric complex are bridged by the O atoms of the phenolate anions, and the coordination geometry around each Zn atom is distorted square-based pyramidal. The two Cl atoms lie on the same side of the central Zn~2~O~2~ plane.

📜 SIMILAR VOLUMES

Bis­[2-(cyclo­propyl­imino­methyl)­pheno
Bis­[2-(cyclo­propyl­imino­methyl)­phenolato]­zinc(II)
✍ You, Zhong-Lu ;Lin, Yong-Shan ;Liu, Wei-Sheng ;Tan, Min-Yu ;Zhu, Hai-Liang 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 240 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.019 A Ê R factor = 0.055 wR factor = 0.159 Data-to-parameter ratio = 13.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Dibromo­{4-chloro-2-[(2-diethyl­amino­et
Dibromo­{4-chloro-2-[(2-diethyl­amino­ethyl­imino)meth­yl]phenolato}zinc(II)
✍ Wei, Yi-Jun ;Wang, Feng-Wu ;Zhu, Qi-Yong 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 128 KB

The title compound, [ZnBr~2~(C~13~H~19~ClN~2~O)], is a mononuclear Schiff base zinc(II) complex. The Zn atom in the compound is four-coordinated by one imine N and one phenolate O atom of the Schiff base ligand and by two terminal bromide anions in a tetrahedral geometry. In the crystal structure, m