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catena-Poly­[[[4-bromo-2-(2-di­methyl­amino­ethyl­imino­methyl)­phenolato]­zinc(II)]-μ-thio­cyanato]

✍ Scribed by Yue, Guo-Ren ;Lei, Xin-You ;Xu, Xin-Jian ;Xue, Guo-Qing

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
298 KB
Volume
61
Category
Article
ISSN
1600-5368

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.033 wR factor = 0.086 Data-to-parameter ratio = 20.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Bis{μ2-2-[2-(dimethyl­amino)ethyl­imino­
Bis{μ2-2-[2-(dimethyl­amino)ethyl­imino­methyl]phenolato}bis­[chloro­zinc(II)]
✍ Chen, Hsuan-Ying ;Lin, Chu-Chieh 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 131 KB

The title complex, [Zn~2~(C~11~H~15~N~2~O)~2~Cl~2~] or [__L__ZnCl]~2~, where __L__ is the 2-[2-(dimethylamino)ethyliminomethyl]phenolate anion, is obtained by the reaction of __L__ZnEt with CDCl~3~ or by the reaction of __L__H with ZnCl~2~ in refluxing tetrahydrofuran. The Zn atoms in the dimeric co