catena-Poly[[[diaquacadmium(II)]-di-μ-thiocyanato] bis(2-amino-4,6-dimethylpyrimidine)]
✍ Scribed by Muthiah, Packianathan Thomas ;Hemamalini, Madhukar ;Butcher, Ray J.
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 265 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.033 wR factor = 0.086 Data-to-parameter ratio = 20.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê R factor = 0.054 wR factor = 0.125 Data-to-parameter ratio = 14.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Cd("-SCN) 2 (C 7 H 7 NO 2 ) 2 ] n , has been prepared from the reaction of 3-aminobenzoic acid, NH 4 SCN and Cd(NO 3 ) 2 Á6H 2 O in MeOH/H 2 O. It consists of onedimensional polymeric chains, which are extended into a two-dimensional layer structure by head-to-head hydrogen bond
Reaction of Co(NCS) 2 and 2-aminobenzonitrile (ABN) produces the title one-dimensional polymer, [Co(NCS) 2 -(ABN) 2 ] n , where ABN is 2-aminobenzonitrile (C 7 H 6 N 2 ). Octahedrally coordinated Co II ions are bridged by the ABN molecules, which are coordinated to the central metal via the N donors