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Bis[2-(4,5-dihydro-1H-imidazol-2-yl)phenolato-κ2N,O]nickel(II)

✍ Scribed by He, Hong-Shan

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
125 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [Ni(C 9 H 9 N 2 O) 2 ], the Ni 2+ ion is coordinated by two 2-(4,5-dihydro-1H-imidazol-2-yl)phenolate ligands. Each ligand provides one O atom and one N atom to the Ni coordination, giving a total coordination number of 4. The centrosymmetric complex adopts a square-planar geometry.

📜 SIMILAR VOLUMES

Bis[2-(1H-imidazol-2-yl)phenolato-κ2N,O]
Bis[2-(1H-imidazol-2-yl)phenolato-κ2N,O]zinc(II) methanol solvate
✍ He, Hong-Shan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 184 KB

In the title complex, [Zn(C 18 H 14 N 4 O 2 )]ÁCH 3 OH, two anionic 2-(1H-imidazol-2-yl)phenolate bidentate ligands coordinate through the phenolate O and imidazolyl N atoms to the central Zn II atom to give a four-coordinate tetrahedral geometry.

trans-Bis[2-(4-ethyl-4,5-dihydro-1,3-oxa
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✍ Zhang, Yan ;Kong, Di ;Liu, Tian-Fu ;Xu, Wen-Guo 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 826 KB

In the title compound, [Mn(C 11 H 12 NO 2 ) 2 (NCS)], the coordination polyhedron of the Mn III atom has a distorted squarepyramidal geometry, with the two phenolate ligands coordinated in the basal plane in trans positions and the thiocyanate ion coordinated at the apical position.

Bis[2-(benzimidazol-2-yl)phenolato-κ2N,O
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In the title compound, [Co(C 13 H 9 N 2 O) 2 ], the coordination geometry of the Co II atom is distorted tetrahedral; the Co atom lies on a twofold axis. Adjacent molecules are linked by N-HÁ Á ÁO hydrogen bonds into a three-dimensional network structure.