𝔖 Bobbio Scriptorium
✦   LIBER   ✦

trans-Bis[2-(4-ethyl-4,5-dihydro-1,3-oxazol-2-yl)phenolato-κ2N,O](thiocyanato-κN)manganese(III)

✍ Scribed by Zhang, Yan ;Kong, Di ;Liu, Tian-Fu ;Xu, Wen-Guo


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
826 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis


In the title compound, [Mn(C 11 H 12 NO 2 ) 2 (NCS)], the coordination polyhedron of the Mn III atom has a distorted squarepyramidal geometry, with the two phenolate ligands coordinated in the basal plane in trans positions and the thiocyanate ion coordinated at the apical position.


📜 SIMILAR VOLUMES


trans-Bis{2-[3-(cyclohexylamino)propylim
✍ Chen, Kun ;Zhang, Ying-Lao ;Feng, Ming-Qian ;Liu, Chang-Hong 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 705 KB

The title complex, [Fe(NCS) 2 (C 32 H 46 N 4 O 2 ) 2 ], is a mononuclear iron(II) complex with a distorted octahedral coordination geometry and the central Fe 2+ ion, located on an inversion centre, is coordinated by four N atoms and two O atoms from two Schiff-base ligands and two thiocyanate anion

Bis[2-(4,5-dihydro-1H-imidazol-2-yl)phen
✍ He, Hong-Shan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 125 KB

In the title complex, [Ni(C 9 H 9 N 2 O) 2 ], the Ni 2+ ion is coordinated by two 2-(4,5-dihydro-1H-imidazol-2-yl)phenolate ligands. Each ligand provides one O atom and one N atom to the Ni coordination, giving a total coordination number of 4. The centrosymmetric complex adopts a square-planar geom

{4-Bromo-2-[2-(ethylamino)ethyliminometh
✍ Zhou, Zhi ;Tang, Rui-Ren 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 306 KB

In the title compound, [Cu(C 11 H 14 BrN 2 O)(NCS)], the Cu atom is four-coordinated by the NNO donor set of the Schiff base ligand and by the terminal N atom of the thiocyanate anion, forming a square-planar geometry. An N-HÁ Á ÁS hydrogen bond helps to establish the packing.

Bis(μ-3,5-di-2-pyridyl-1,2,4-triazolato-
✍ Jiang, Gang-Biao ;Zeng, Xin-Nian ;Fang, Yu-Sheng ;Zeng, Ming-Hua ;Ng, Seik Weng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 958 KB

In the title centrosymmetric dinuclear iron(II) compound, [Fe 2 (C 12 H 8 N 5 ) 2 (NCS) 2 (CH 4 O) 2 ], the deprotonated 3,5-di-2pyridyl-1,2,4-triazole ligand uses a pair of N pyridyl /N triazolyl atoms to chelate one metal atom and the other pair of N pyridyl / N triazolyl atoms to chelate the othe