The title complex, [Fe(NCS) 2 (C 32 H 46 N 4 O 2 ) 2 ], is a mononuclear iron(II) complex with a distorted octahedral coordination geometry and the central Fe 2+ ion, located on an inversion centre, is coordinated by four N atoms and two O atoms from two Schiff-base ligands and two thiocyanate anion
trans-Bis[2-(4-ethyl-4,5-dihydro-1,3-oxazol-2-yl)phenolato-κ2N,O](thiocyanato-κN)manganese(III)
✍ Scribed by Zhang, Yan ;Kong, Di ;Liu, Tian-Fu ;Xu, Wen-Guo
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 826 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [Mn(C 11 H 12 NO 2 ) 2 (NCS)], the coordination polyhedron of the Mn III atom has a distorted squarepyramidal geometry, with the two phenolate ligands coordinated in the basal plane in trans positions and the thiocyanate ion coordinated at the apical position.
📜 SIMILAR VOLUMES
In the title complex, [Ni(C 9 H 9 N 2 O) 2 ], the Ni 2+ ion is coordinated by two 2-(4,5-dihydro-1H-imidazol-2-yl)phenolate ligands. Each ligand provides one O atom and one N atom to the Ni coordination, giving a total coordination number of 4. The centrosymmetric complex adopts a square-planar geom
In the title compound, [Cu(C 11 H 14 BrN 2 O)(NCS)], the Cu atom is four-coordinated by the NNO donor set of the Schiff base ligand and by the terminal N atom of the thiocyanate anion, forming a square-planar geometry. An N-HÁ Á ÁS hydrogen bond helps to establish the packing.
In the title centrosymmetric dinuclear iron(II) compound, [Fe 2 (C 12 H 8 N 5 ) 2 (NCS) 2 (CH 4 O) 2 ], the deprotonated 3,5-di-2pyridyl-1,2,4-triazole ligand uses a pair of N pyridyl /N triazolyl atoms to chelate one metal atom and the other pair of N pyridyl / N triazolyl atoms to chelate the othe