Diaquabis[4-(3-pyridyl)-1H-1,2,4-triazole]dithiocyanatomanganese(II)
✍ Scribed by Li, Hui ;Li, Chang-Jin ;Hu, Zhi-Qiang
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 132 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Single-crystal X-ray study T = 294 K Mean (C-C) = 0.005 A R factor = 0.045 wR factor = 0.120 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
The molecular structure of the neutral mononuclear title complex, [Mn(NCS) 2 (C 12 H 8 N 4 O) 2 (H 2 O) 2 ], is centrosymmetric; the Mn II atom lies on an inversion center and is sixcoordinate (MnN 4 O 2 ), with an octahedral geometry comprising two trans monodentate 2,5-di-3-pyridyl-1,3,4oxadiazole
The coordination geometry of the Co II atom in the title complex, [Co(NCO) 2 (C 12 H 12 N 6 ) 2 ] n or [Co(NCO) 2 (bbtz) 2 ] n , where bbtz is 1,4-bis(1,2,4-triazol-1-methyl)benzene, is distorted octahedral, in which the Co II atom lies on an inversion centre and is coordinated by four N atoms from
The title compound, C 20 H 14 N 12 S 2 , was synthesized by the reaction of 3-hydrazino-1H-1,2,4-triazole with phenyl isocyanate in benzene and by ring closure in an alkaline medium. Intermolecular N-HÁ Á ÁN hydrogen bonds are observed and these form a five-membered ring.
In the title compound, C 15 H 14 N 4 OÁ2H 2 O, the 1,2,4-triazole, pyridine and benzene rings do not share a common plane. The crystal structure is stabilized by O-HÁ Á ÁN and O-HÁ Á ÁO intermolecular hydrogen-bond interactions.