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Diaqua­bis(2,5-di-3-pyrid­yl-1,3,4-oxadiazole)dithio­cyanato­manganese(II): a three-dimensional supra­molecular network formed through O—H⋯N and C—H⋯S inter­actions

✍ Scribed by Du, Miao ;Jiang, Xiu-Juan ;Zhao, Xiao-Jun

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
275 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The molecular structure of the neutral mononuclear title complex, [Mn(NCS) 2 (C 12 H 8 N 4 O) 2 (H 2 O) 2 ], is centrosymmetric; the Mn II atom lies on an inversion center and is sixcoordinate (MnN 4 O 2 ), with an octahedral geometry comprising two trans monodentate 2,5-di-3-pyridyl-1,3,4oxadiazole ligands, two thiocyanate ligands and two bound water molecules. Intermolecular O-HÁ Á ÁN hydrogen bonds between these monomeric units result in two-dimensional supramolecular layers with a parallel arrangement, which are stabilized by intralayer aromatic stacking and further extended to a three-dimensional network via interlayer weak C-HÁ Á ÁS interactions.

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