In the title centrosymmetric dinuclear complex, [Ni 2 (NCS) 2 -(C 10 H 15 N 3 ) 2 ](ClO 4 ) 2 , each Ni II ion is pentacoordinated by the pyridine N, imine N, and amine N atoms of the Schiff base ligand, and by the terminal N and S atoms from two bridging thiocyanate ligands, forming a slightly dist
{Dimethyl [2,2′-(ethane-1,2-diyldioxy)bis(benzylidenehydrazono)]bis(dithioformato)-κ4S,N,N′,S′}copper(II)
✍ Scribed by Mei, Guang-Quan ;Huang, Ke-Long
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 914 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
{Dimethyl [2,2 0 0 0 -(ethane-1,2-diyldioxy)bis(benzylidenehydrazono)]bis(dithioformato)-j 4 S,N,N 0 0 0 ,S 0 0 0 }copper(II)
📜 SIMILAR VOLUMES
The title complex, [Cu 2 (N 3 ) 4 (C 5 H 14 N 2 ) 2 ], is a centrosymmetric dimer in which each Cu atom is coordinated by five N atoms from three azide anions and one N,N-dimethyl-1,3-propylenediamine molecule in a distorted square-pyramidal geometry; the CuÁ Á ÁCu distance is 3.416 (1) A ˚.
Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.003 A Ê R factor = 0.036 wR factor = 0.093 Data-to-parameter ratio = 27.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.005 A Ê R factor = 0.041 wR factor = 0.100 Data-to-parameter ratio = 25.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.