The title compound, [Ni(C 8 H 5 O 3 ) 2 (C 3 H 4 N 2 ) 2 (H 2 O) 2 ], is isostructural with the manganese analogue. The Ni atom, which lies on a centre of inversion, is coordinated by two imidazole and two water ligands, as well as by the formylbenzoate groups, in an all-trans octahedral geometry.
{[N,N′-Bis(4-methoxybenzyl)ethane-1,2-diyldiimino]diacetato}bis(1H-imidazole-κN3)nickel(II)
✍ Scribed by Zhang, Min ;Weng, Hui-Li ;Xu, Xing-Man
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 252 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 297 K Mean (C-C) = 0.005 A R factor = 0.050 wR factor = 0.131 Data-to-parameter ratio = 16.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê Disorder in main residue R factor = 0.027 wR factor = 0.070 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title complex, [Ni 2 Br 2 (C 2 H 8 N 2 ) 4 ]Br 2 , consists of two bromide anions and a complex dication. The dication is a centrosymmetric unit of two Ni atoms bridged unsymmetrically by two Br atoms. The Ni atoms are pseudo-octahedral, six-coordinate, with four N atoms from two 1,2-diaminoetha