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cis-Bis(8-hydroxy­quinolinato-κ2N,O)­di­phenyl­tin(IV)

✍ Scribed by Linden, Anthony ;Basu Baul, Tushar S. ;Mizar, Archana

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
186 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The coordination geometry at the Sn atom in the title compound, [Sn(C 6 H 5 ) 2 (C 9 H 6 NO) 2 ], is distorted cis-octahedral, in which the two phenyl ligands are cis to one another and trans to the N atoms of the oxinate ligands. This arrangement brings the oxinate O atoms into a trans relationship and is the geometry adopted most frequently by diorganotin(IV) oxinates. The OÁ Á ÁO vector in the molecule is almost parallel to the plane of every ligand.

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