Tris(8-hydroxyquinolinato-κ2O,N)oxoniobium(V) dichloromethane disolvate
✍ Scribed by Amini, Mostafa M. ;Mirzaee, Mehdi ;Yeganeh, Farnaz ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 188 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 163 K Mean '(C±C) = 0.005 A Ê R factor = 0.036 wR factor = 0.097 Data-to-parameter ratio = 14.9
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📜 SIMILAR VOLUMES
The coordination geometry at the Sn atom in the title compound, [Sn(C 6 H 5 ) 2 (C 9 H 6 NO) 2 ], is distorted cis-octahedral, in which the two phenyl ligands are cis to one another and trans to the N atoms of the oxinate ligands. This arrangement brings the oxinate O atoms into a trans relationship
Molecules of the title compound, [Rh(C 9 H 6 NO)(C 18 F 15 P)-(CO)], pack in a tail-to-tail fashion, with an intermolecular ligand-to-ligandstacking distance of 3.399 (8) A ˚. The effective cone angle (Â E ) for the phosphine ligand is 163 . The bite angle of the bidentate oxine ligand is 80.77 (10)