Carbon­yl(8-hydroxy­quinolinato-κ2N,O)[tris­(2,3,4,5,6-penta­fluoro­phenyl)phosphine-κP]rhodium(I)

✍ Scribed by Janse van Rensburg, J. Marthinus ;Roodt, Andreas

• Publisher: International Union of Crystallography
• Year: 2006
• Tongue: English
• Weight: 227 KB
• Volume: 62
• Category: Article
• ISSN: 1600-5368
• DOI: 10.1107/s1600536806040190

✦ Synopsis

Molecules of the title compound, [Rh(C 9 H 6 NO)(C 18 F 15 P)-(CO)], pack in a tail-to-tail fashion, with an intermolecular ligand-to-ligandstacking distance of 3.399 (8) A ˚. The effective cone angle (Â E ) for the phosphine ligand is 163 . The bite angle of the bidentate oxine ligand is 80.77 (10) and the Rh-P bond length is 2.2145 (11) A ˚.