The hydroxyquinolinate group chelates to the Ti atom in the centrosymmetric title compound, [Ti 2 (C 9 H 6 NO) 2 (C 2 H 5 O) 6 ]. Two of the four ethoxy groups function as bridges, and the geometry of the six-coordinate Ti atom is that of an octahedron.
Di-μ-isopropoxy-bis[(8-hydroxyquinolinolato)diisopropoxyzirconium(IV)]
✍ Scribed by Amini, Mostafa M. ;Mahmoodi, Ayoob ;Mirzaee, Mehdi ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 217 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Single-crystal X-ray study T = 163 K Mean '(C±C) = 0.004 A Ê R factor = 0.032 wR factor = 0.082 Data-to-parameter ratio = 19.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
The Hf IV atoms in the centrosymmetric title compound, (C 4 H 12 N) 2 ][Hf 2 F 10 (H 2 O) 2 ], are bridged by two F atoms. The Hf IV atoms show pentagonal-bipyramidal coordination. The dianions are linked by water-fluorine hydrogen bonds into layers.
The title compound, [Zr~2~Cl~8~(C~6~H~6~ClN)~2~], is centrosymmetric. Each Zr^IV^ ion has distorted octahedral coordination geometry, formed by one N atom from a 4-chloroaniline ligand, three terminal Cl^−^ ions and two bridging Cl^−^ ions. The Zr—μ-Cl bond distances are much longer than the other Z
In the title compound, [Sn~2~Cl~6~(OH)~2~(H~2~O)~2~]·0.5C~6~H~6~·H~2~O, the benzene molecule is located on a centre of inversion. The Sn atoms are in an octahedral environment, each coordinated by three Cl, one water and two briding hydroxide ligands. Two Cl atoms and the hydroxide groups are in the
The crystal structure of the title compound, (C 2 H 10 N 2 )-(C 2 H 9 N 2 ) 2 [Sn 2 S 6 ], consists of discrete [Sn 2 S 6 ] 4À anions and mono-as well as diprotonated ethylenediamine molecules. The anion and the monoprotonated cation occupy general positions, whereas the dications are located on cen