A high-yield synthesis toward 5,5 -bis(silyl)-functionalized 3,3 -dibromo-2,2 -dithiophenes with very efficient work-up procedure is presented. The molecular structures of two silyl functionalized dibromo-dithiophenes in the solid state have been determined to investigate the structural influences o
✦ LIBER ✦
Synthesis, spectroscopic and X-ray single-crystal structure study of bis(2-methoxy-ethanolato)-bis(8-quinolinato)titanium(IV)
✍ Scribed by M. Mirzaee; M. M. Amini
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 102 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.840
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The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ĹnBH 4