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Steric and Electronic Effects of Chelating Phosphines: Synthesis, Spectral, and Single Crystal X-Ray Structural Studies on [1,3-Bis(diphenylphosphino-k,P,P′)propane](diisopropyldithiocarbamato)nickel(II) Perchlorate and [1,3-Bis(diphenylphosphino-k,P,P′)propane](piperidinecarbodithioato)nickel(II) Perchlorate

✍ Scribed by A. Manohar; K. Ramalingam; R. Thiruneelakandan; G. Bocelli; Lara Righi

Publisher
John Wiley and Sons
Year
2001
Tongue
German
Weight
128 KB
Volume
627
Category
Article
ISSN
0372-7874

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✍ R. Thiruneelakandan; K. Ramalingam; A. Manohar; G. Bocelli; Lara Righi 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 163 KB 👁 1 views

X-ray photoelectron spectral study was made on the complexes Ni(nmedtc) 2 (1), [Ni(nmedtc)(PPh 3 ) 2 ]ClO 4 (2), [Ni-(nmedtc)(dppe)]BPh 4 (3) (where nmedtc ϭ N-methyl,N-ethanoldithiocarbamate, dppe ϭ 1,2-bis(diphenylphosphino)ethane). The nickel 2p 3/2 binding energy values for chelated and free pho