μ-Oxo-bis[trichlorobis(dimethylsulfane)titanium(IV)]
✍ Scribed by Schormann, Mark
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 192 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The structure of [Ti 2 Cl 6 O(Me 2 S) 4 ] shows a distorted octahedral arrangement around the Ti atom. The molecule does not possess an inversion centre at the O atom.
📜 SIMILAR VOLUMES
Bis{tri-l-chloro-bis[(g 6 -p-cymene)ruthenium(II)]} di-l-chloro-bis[dichloromercurate(II)]
Single-crystal X-ray study T = 173 K Mean (C-C) = 0.005 A Disorder in main residue R factor = 0.054 wR factor = 0.139 Data-to-parameter ratio = 21.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Ti 2 ( 5 -C 5 H 5 ) 4 (N 3 ) 2 O], is a dinuclear oxobridged azido complex with two titanocene fragments connected through the oxygen bridge. The environment around each Ti atom can be considered as a distorted tetrahedron.
The title compound, [Zr~2~Cl~8~(C~6~H~6~ClN)~2~], is centrosymmetric. Each Zr^IV^ ion has distorted octahedral coordination geometry, formed by one N atom from a 4-chloroaniline ligand, three terminal Cl^−^ ions and two bridging Cl^−^ ions. The Zr—μ-Cl bond distances are much longer than the other Z
Single-crystal X-ray study T = 220 K Mean '(C±C) = 0.005 A Ê R factor = 0.034 wR factor = 0.089 Data-to-parameter ratio = 17.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.