𝔖 Bobbio Scriptorium
✦   LIBER   ✦

μ-Oxo-bis­[azido­bis(η5-cyclo­penta­dienyl)­titanium(IV)]

✍ Scribed by Honzíček, Jan ;Vinklárek, Jaromír ;Erben, Milan ;Císařová, Ivana

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
197 KB
Volume
60
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, [Ti 2 ( 5 -C 5 H 5 ) 4 (N 3 ) 2 O], is a dinuclear oxobridged azido complex with two titanocene fragments connected through the oxygen bridge. The environment around each Ti atom can be considered as a distorted tetrahedron.

📜 SIMILAR VOLUMES

μ2-Oxo-bis­[bis(η5-1,3-di-tert-butylcycl
μ2-Oxo-bis­[bis(η5-1,3-di-tert-butylcyclo­penta­dienyl)­titanium(III)]
✍ Sofield, Chadwick D. ;Walter, Marc D. ;Andersen, Richard A. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 241 KB

The title compound, [Ti 2 O(C 13 H 21 ) 4 ] or {[(1,3-t Bu 2 -C 5 H 3 ) 2 Ti} 2 (" 2 -O)}, crystallizes as a centrosymmetric molecule, in which the two metallocene fragments are bridged by an O atom. The trigonal planar coordination around each metal consists of two 1,3-t Bu 2 C 5 H 3 ligands and th

Bis(η5-cyclo­penta­dienyl)­bis­(thio­cya
Bis(η5-cyclo­penta­dienyl)­bis­(thio­cyanato-κN)­vanadium(IV)
✍ Honzíček, Jan ;Erben, Milan ;Císařová, Ivana ;Vinklárek, Jaromír 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 197 KB

In the crystal structure of the title vanadocene complex, [V( 5 -C 5 H 5 ) 2 (NCS) 2 ], the V atom has distorted tetrahedral coordination with two 5 -bonded cyclopentadienyl rings and two Nbonded thiocyanate ligands.

[η5-1,2-Bis(4-nitro­phenyl)­cyclo­penta­
[η5-1,2-Bis(4-nitro­phenyl)­cyclo­penta­dienyl](η5-cyclo­penta­dienyl)­iron
✍ McAdam, C. John ;Robinson, Brian H. ;Simpson, Jim 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 220 KB

The title compound, 1,2-bis(4-nitrophenyl)ferrocene, [Fe(C 5 H 5 )(C 17 H 11 N 2 O 4 )], crystallizes with the planes of the two vicinal 4-nitrophenyl rings subtending angles of 46.04 (6) and 36.30 (7) at the plane of the substituted cyclopentadiene ring of the ferrocene moiety.