The title compound, [Ti 2 ( 5 -C 5 H 5 ) 4 (N 3 ) 2 O], is a dinuclear oxobridged azido complex with two titanocene fragments connected through the oxygen bridge. The environment around each Ti atom can be considered as a distorted tetrahedron.
Bis(η5-cyclopentadienyl)bis(thiocyanato-κN)vanadium(IV)
✍ Scribed by Honzíček, Jan ;Erben, Milan ;Císařová, Ivana ;Vinklárek, Jaromír
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 197 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the crystal structure of the title vanadocene complex, [V( 5 -C 5 H 5 ) 2 (NCS) 2 ], the V atom has distorted tetrahedral coordination with two 5 -bonded cyclopentadienyl rings and two Nbonded thiocyanate ligands.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 137 K Mean '(C±C) = 0.005 A Ê R factor = 0.048 wR factor = 0.134 Data-to-parameter ratio = 18.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, 1,2-bis(4-nitrophenyl)ferrocene, [Fe(C 5 H 5 )(C 17 H 11 N 2 O 4 )], crystallizes with the planes of the two vicinal 4-nitrophenyl rings subtending angles of 46.04 (6) and 36.30 (7) at the plane of the substituted cyclopentadiene ring of the ferrocene moiety.