Acetonitrilechlorotris(η5-cyclopentadienyl)vanadium(IV) tetrachloroferrate(III)
✍ Scribed by Honzíček, Jan ;Císařová, Ivana ;Vinklárek, Jaromír
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 199 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the cation of the title compound, [Rh 2 Cl 3 (C 10 H 15 ) 2 ]BF 4 , two Rh( 5 -C 5 Me 5 ) fragments are linked by three bridging Cl atoms. Each rhodium center has a pseudo-octahedral coordination geometry, with a C 5 Me 5 group occupying three positions and three Cl atoms completing the coordinat
Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.004 A Ê R factor = 0.026 wR factor = 0.064 Data-to-parameter ratio = 23.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the crystal structure of the title vanadocene complex, [V( 5 -C 5 H 5 ) 2 (NCS) 2 ], the V atom has distorted tetrahedral coordination with two 5 -bonded cyclopentadienyl rings and two Nbonded thiocyanate ligands.
Single-crystal X-ray study T = 137 K Mean '(C±C) = 0.005 A Ê R factor = 0.048 wR factor = 0.134 Data-to-parameter ratio = 18.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.